Compounds containing 1-aza-3-oxa-4-silacyclohex-1-enyl groups, a

Details Compounds containing 1-aza-3-oxa-4-silacyclohex-1-enyl groups, a Compounds containing 1-aza-3-oxa-4-silacyclohex-1-enyl groups, a

1994-12-16

1995-08-29

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556400, 556419, 556465, 528 32, C07F 710

Patent

active

054461804

ABSTRACT:
Novel 1-aza-3-oxa-4-silacyclohex-1-ene compounds, and tautomers thereof, having utility as chemical modifiers or cross linkers for hydroxy-containing organic or inorganic substances are disclosed, said compounds being represented by the general formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each independently denotes a monovalent organic group having 1 to 6 carbon atoms selected from the group consisting of saturated hydrocarbon groups and unsaturated hydrocarbon groups, R.sup.3 deontes an organic group having 1 to 30 carbon atoms selected from the group consisting of saturated hydrocarbon groups and unsaturated hydrocarbon groups, said R.sup.3 groups optionally containing a heteroatom selected from the group consisting of oxygen, nitrogen, sulfur, silicon, fluorine, chlorine, bromine and iodine, Me denotes a methyl radical and n is an integer having a value of 1 to 4.

REFERENCES:
patent: 3479383 (1969-11-01), Klebe
patent: 3655615 (1972-04-01), Bush et al.
patent: 3677977 (1972-07-01), Bush et al.
patent: 3755398 (1973-08-01), Bush
patent: 4794192 (1988-12-01), Stein
Platinum-Catalyzed Intramolecular Hydrosilation of Allylamines: Formation of 1-Aza-2-silocyclobutanes and application to Stereoselective Synthesis of 2-Amino Alcohols, J. Org. Chem., 1990, 55, 3438-3439.

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