Optically active compounds and a method for producing them

Details Optically active compounds and a method for producing them Optically active compounds and a method for producing them

1994-07-19

1995-08-29

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549513, 568312, 568315, 568343, 568347, 568373, C07D30100, C07D30332, C07D 49527

Patent

active

054461758

ABSTRACT:
The present invention provides special epoxy derivative (1), cyclohexanone derivative (2), cyclohexenone derivative (3) and 3-substituted cyclohexenone derivative (4) which are useful as intermediates for synthesizing physiologically active materials, and a method for stereoselectively introducing substituted groups. Further, the present invention provides a method for synthesizing optically active compounds, such as optically active carvone via these intermediates. ##STR1##

REFERENCES:
patent: 3979338 (1976-09-01), Sundt
patent: 4031237 (1977-06-01), Gough et al.
patent: 4642361 (1987-02-01), Ruttimann
Nomura et al, Hydration Of Several Monoterpene Hydrocarbons With Water In The Presence Of Synthetic Zeolites The Chemical Society of Japan, (1), 1992, p. 63-67.
Asaoka, et al, Enantioselective Routes To 2, 5-Disubstituted-And 4-Substitued-2-Cyclohexenones, Tetrahedron Letters, Vol. 30, No. 50, pp. 7075-7078, 1989.

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