Method for preparing polyperoxydicarbonate esters

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 6800, C07C 6996

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039352439

ABSTRACT:
Dialkyl alkylenebis(peroxydicarbonates) and oxyalkylenebis(peroxydicarbonates) and corresponding higher polyfunctional peroxydicarbonic acid esters are useful initiators of vinyl polymerization. These compounds are prepared by reacting a sodium alkylperoxycarbonate with a diol bis(chloroformate) at from about -10.degree.C to about 20.degree.C.

REFERENCES:
strain, et al., J.A.C.S., 72 (1950), pp. 1254-1263.

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