Preparing poly (arylene ketone) with liquefaction agent treatmen

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528125, 528128, 528176, 528179, 528180, 528181, 528182, 528193, 528194, C08G 8500, C08G 6538

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active

046651519

ABSTRACT:
The preparation of poly(arylene ketones) and in particular all para-linked poly(arylene ether ketones) by Friedel-Crafts polymerization in the presence of a Lewis acid generally results in an intractible reaction product difficult to remove from the reaction vessel and difficult to purify. The addition of a liquefaction agent, such as a hydrogen halide and in particular hydrogen chloride, to the reaction mixture, results in a tractible gel or a liquid which can be readily handled. The hydrogen halide is preferably under pressure and a diluent may also be added along with the hydrogen halide.

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