Synthesis of ethanol by homologation of methanol

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 2700

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043742858

ABSTRACT:
Ethanol is prepared by contacting methanol, hydrogen and carbon monoxide with a catalyst system comprising a ruthenium compound, a quaternary phosphonium or ammonium base or salt and a cobalt compound such as cobalt iodide.

REFERENCES:
patent: 3285948 (1966-11-01), Butter
patent: 4239924 (1980-12-01), Pretzer et al.
patent: 4277634 (1981-07-01), Walker

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