Photochemical synthesis of allenic and propargylic organomercuri

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415798, 20415799, 20415812, B01J 1912

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active

046647651

ABSTRACT:
Propargylic halides, preferably the bromide and iodide, react with metallic mercury in a finely divided state, in the presence of sunlight to form the corresponding allenic or propargylic organomercuric halides in high yield.

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M. Gaudemar, Bul. Soc. Chim. France, 1962, 974.
L. Henry, Ber.Dt.Chem.Ges., 1884, 17, 1132.

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