Method for the preparation of a polyhalogeno metal complex compo

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 45, 556 64, 556 81, 556110, 556118, 556138, 556170, C07F 100, C07F 300, C07F 500

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058471740

ABSTRACT:
Proposed is a method for the preparation of an ionic polyhalogeno metal complex compound consisting of a tetraalkylammonium cation and a polyhalogeno metal anion, of which the metal is selected from those having an atomic valency of 1 and a coordination number of 2, those having an atomic valency of 3 and a coordination number of 4 and those having an atomic valency of 2 and a coordination number of 4. The method comprises the steps of: dissolving a tetraalkylammonium halide and elementary halogen in a stoichiometric proportion corresponding to the chemical composition of the desired complex compound in an organic solvent to form a solution; dissolving, in the solution, the metal in an amount larger than the stoichiometric amount so as to be dissolved in the solution forming the complex compound in the reaction mixture; removing the undissolved metal from the reaction mixture to give a solution of the complex compound; and isolating the complex compound from the solution.

REFERENCES:
Chemical Abstracts, vol. 114, Abstract No. 197391, 1990.

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