Production of esters

Details Production of esters Production of esters

1985-02-25

1987-04-14

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

2604106, 2604109N, 2604109R, 260413, 560 1, 560 8, 560 92, 560129, 560204, 560243, 560245, 560261, 560263, 560265, 560244, 562406, 562497, 562519, 568877, 568909, C07C 5112, C07C 6703, C07C 6738

Patent

active

046580530

ABSTRACT:
A process for the production of an ester comprises reacting an olefin with carbon monoxide, hydrogen and another ester at elevated temperature and pressure in the presence of a catalyst comprising (1) a rhodium source, (2) a ruthenium source, and (3) cobalt or zinc iodide. The product ester comprises the acid group of the ester used as reactant esterified with a hydrocarbyl group derived from the olefin, hydrogen and carbon monoxide.

REFERENCES:
patent: 2644844 (1953-07-01), Brooks et al.
patent: 4417077 (1983-11-01), Drago et al.
patent: 4431835 (1984-02-01), Gauthier-Lafaye et al.

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