Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide
Patent
1994-06-02
1996-07-16
Dudash, Diana
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Metal, metal oxide or metal hydroxide
502245, 502326, 502328, 502330, 502331, 502339, B01J 2344, B01J 3708
Patent
active
055366937
ABSTRACT:
A process of producing a fluid bed oxacylation catalyst for olefins and diolefins having the following formula Pd-M-A where
M=Au, Cd, Bi, Cu, Mn, Fe, Co, Ce, U and mixtures thereof,
A=an alkali metal or mixture thereof, and
M is present in the range of from 0 to 5 wt %, comprising milling a fixed bed oxacylation catalyst precursor comprising Pd-M on a fixed support with a fluid bed catalyst aqueous binder material to form a uniform aqueous slurry, drying the aqueous slurry to remove the water to form microspheroidal particles of solid fluid bed catalyst precursor, impregnating the microspheroidal particles with a solution of alkali metal salt to form the fluid bed catalyst. The catalyst is particularly useful in the manufacture of vinyl acetate from ethylene, acetic acid and oxygen.
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Blum Patricia R.
Cirjak Larry M.
Lemanski Michael F.
Paparizos Christos
Pepera Marc A.
Dudash Diana
Esposito Michael F.
Meeks Timothy H.
The Standard Oil Company
Untener David J.
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