CO/olefin polymerization with carboxylic acid or phenol

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymer of an ethylenically unsaturated reactant with a...

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502162, C08G 6702

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active

052294757

ABSTRACT:
A novel catalyst composition containing a palladium salt, an anion of a non-hydrohalogenic acid with a pk.sub.a of less than 2, a phosphorus bidentate ligand and an acid with a pk.sub.a of at least 4 but less than 6. The catalyst composition effectively polymerizes carbon monoxide and at least one ethylenically unsaturated hydrocarbon to produce linear, alternating polymers.

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patent: 4843144 (1989-06-01), Van Broekhoven et al.
patent: 4868282 (1989-09-01), Van Broekhoven et al.
patent: 4880903 (1989-11-01), Van Broekhoven et al.

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