Electrophotographic light-sensitive material

Details Electrophotographic light-sensitive material Electrophotographic light-sensitive material

1991-05-23

1993-07-20

McCamish, Marion E.

Radiation imagery chemistry: process, composition, or product th

Electric or magnetic imagery, e.g., xerography,...

Radiation-sensitive composition or product

430 49, 430 87, G03G 5087

Patent

active

052292410

ABSTRACT:
An electrophotographic light-sensitive material comprising a support having provided thereon a photoconductive layer containing at least an inorganic photoconductive substance, a spectral sensitizer and a binder resin, wherein the binder resin contains (1) at least one resin (Resin (A)) having a weight average molecular weight of from 1.times.10.sup.3 to 1.times.10.sup.4 which contains at least 30% by weight of a polymer component represented by the general formula (I) described below and from 0.1 to 10% by weight of a polymer component containing at least one acidic group selected from --PO.sub.3 H.sub.2, --SO.sub.3 H, --COOH, ##STR1## (wherein R represents a hydrocarbon group or --OR' (wherein R' represents a hydrocarbon group), and a cyclic acid anhydride-containing group, and which has at least one acidic group selected from the above-described acidic groups at one terminal of the main chain of the copolymer; ##STR2## wherein a.sub.1 and a.sub.2 each represents a hydrogen atom, a halogen atom, a cyano group or a hydrocarbon group; and R.sub.1 represents a hydrocarbon group; and (2) at least one copolymer (Resin (B)) formed from at least a monofunctional macromonomer (MB) having a weight average molecular weight of not more than 2.times.10.sup.4 and a monomer represented by the general formula (V) described below, the macromonomer (MB) comprising at least a polymer component corresponding to a repeating unit represented by the general formula (IVa) or (IVb) described below, and the macromonomer (MB) having a polymerizable double bond group represented by the general formula (III) described below bonded to only one terminal of the main chain thereof. ##STR3## wherein V.sub.0 represents --COO--, --OCO--, --CH.sub.2 OCO--, --CH.sub.2 COO--, --O--, --SO.sub.2 --, --CO--, --CONHCOO--, --CONHCONH--, --CONHSO.sub.2 --, ##STR4## (wherein P.sub.0 represents a hydrogen atom or a hydrocarbon group); and c.sub.1 and c.sub.2, which may be the same or different, each represents a hydrogen atom, a halogen atom, a cyano group, a hydrocarbon group, --COO--Z.sub.1 or --COO--Z.sub.1 bonded via a hydrocarbon group (wherein Z.sub.1 represents a hydrocarbon group which may be substituted); ##STR5## wherein V.sub.1 has the same meaning as V.sub.0 in the general formula (III); Q.sub.1 represents an aliphatic group having from 1 to 18 carbon atoms or an aromatic group having from 6 to 12 carbon atoms; d.sub.1 and d.sub.2, which may be the same or different, each has the same meaning as c.sub.1 or c.sub.2 in the general formula (III); and Q.sub.0 represents --CN, --CONH.sub.2, or ##STR6## (wherein T represents a hydrogen atom, a halogen atom, a hydrocarbon an alkoxy group, group or --COOZ.sub.2 (wherein Z.sub.2 represents an alkyl group, an aralkyl group, or an aryl group)); wherein V.sub.2 has the same meaning as V.sub.1 in the general formula (IVa); Q.sub.2 has the same meaning as Q.sub.1 in the general formula (IVa); and e.sub.1 and e.sub.2, which may be the same or different, each has the same meaning as c.sub.1 or c.sub.2 in the general formula (III).

REFERENCES:
patent: 5030534 (1991-07-01), Kato et al.
patent: 5073467 (1991-12-01), Kato et al.
patent: 5104759 (1992-04-01), Kato

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