Process for making 1,3-diols from epoxides

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568811, 568831, C07C 2936, C07C 3120, C07C 3508, C07C 3326

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050535625

ABSTRACT:
A process for manufacturing 1,3-glycols is disclosed. The process comprises reacting an epoxide with synthesis gas in the presence of rhodium, a phosphine, and a lower-alkyl iodide or .beta.-hydroxy lower-alkyl iodide.

REFERENCES:
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patent: 3687981 (1972-08-01), Lawrence et al.
patent: 4873378 (1989-10-01), Murphy et al.
patent: 4873379 (1989-10-01), Murphy
patent: 4935554 (1990-06-01), Murphy et al.
Yokokawa et al., Bulletin of the Chemical Society of Japan, vol. 37, p. 677, 1964.
Synthetic Organic Chemicals, Eastman Kodak, vol. VII, No. 3, Rochester, NY 1934.

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