Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof
Patent
1990-04-10
1991-10-01
Anderson, Harold E.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
From carboxylic acid or derivative thereof
528335, 528339, 528340, 528347, C08G 6940
Patent
active
050534840
ABSTRACT:
Novel polyether amides are produced by reacting a polyethylene glycol diamine and a first dicarboxylic acid or an ester thereof, with a polyoxyalkylene diamine of molecular weight of at least 500 and a second dicarboxylic acid or an ester thereof, where the polyethylene glycol diamine has the formula NH.sub.2 --(CH.sub.2 CH.sub.2 O).sub.x --CH.sub.2 CH.sub.2 --NH.sub.2, where x ranges from 2 to 6, and where the first and second dicarboxylic acid may be the same or different. Suitable dicarboxylic acids include adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, terephthalic acid, isophthalic acid, t-butyl isophthalic acid, and mixtures thereof. Suitable polyethylene glycol diamines include triethylene glycol diamine (JEFFAMINE.RTM. EDR--148 Amine) and tetraethylene glycol diamine (JEFFAMINE.RTM. EDR--192 Amine), among others. Higher molecular weight polyether diamines are used in addition to these polyethylene glycol diamines to give polyether amides useful in making polymers, including fibers, having unusually good water absorbancy properties. The polyether amides are made by mixing equimolar salts of diamine/diacid pairs and then heating the mixture to condense to the polymer.
REFERENCES:
patent: 4713437 (1987-12-01), Pilz et al.
Champion Donald H.
Speranza George P.
Su Wei-Yang
Anderson Harold E.
Mossman David L.
Park Jack H.
Priem Kenneth R.
Texaco Chemical Company
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