Stable pharmaceutical composition of alkaline or alkaline earth

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Heterocyclic carbon compounds containing a hetero ring...

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A61K 31505

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active

052235009

ABSTRACT:
A method for preparing d,1-5-methyltetrahydrofolic acid and the salts thereof of the formula: ##STR1## wherein X is hydrogen, an alkaline metal or alkaline earth metal; by reduction of folic acid with sodium borohydride followed by the methylation of the tetrahydrofolic acid thus obtained with aqueous solutions of formaldehye and sodium borohydride in an inert atmosphere.

REFERENCES:
patent: 2695860 (1954-11-01), Weidenheimer et al.
patent: 2927113 (1960-01-01), D'Amato
patent: 3870719 (1975-03-01), Knott et al.
patent: 4148999 (1979-04-01), Temple, Jr. et al.
patent: 4931442 (1990-06-01), Blum
patent: 4959472 (1990-09-01), Wood et al.
patent: 5173488 (1992-12-01), Haeuer
J. A. Blair and Saunders, "A Convenient Method for the Preparation of d,1-5-Methyltetrahydrofolic Acid (d,1-5-methyl-5,6,7,8,-tetrahydropteroly-L-monoglutamic acid)", Analytical Biochemistry, 34, 376-381 (1970).
Sakami, "Sodium 5-Methyltetrahydrofolate", Biochemical Preparations, No. 10 1963 pp. 103-106.
Gennari, Chem. Abstr. vol. 95 entry 98320p abstracting GB 1572138 (1980).

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