Preparation of aliphatic phosphates

Chemistry of carbon compounds – Dipeptides – e.g. – aspartame – anserine – carnosine – etc.

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C07F 911, C07F 9113

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active

039392295

ABSTRACT:
A process for the preparation of trialkyl and trialkenyl phosphates. The process involves oxidation of the corresponding phosphite with oxygen or an oxygen-containing gas. The oxidation is catalyzed by a metal catalyst such as a transition metal carboxylate, for example, and is carried out at relatively low temperatures.

REFERENCES:
patent: 3136804 (1964-06-01), Hodan et al.
patent: 3333030 (1967-07-01), Baranauckas et al.

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