Preparation of zerovalent phosphine substituted rhodium compound

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252431R, 252431P, 260604H, 423299, 423300, 423301, 423463, 423472, 423644, C07F 1500

Patent

active

039391884

ABSTRACT:
A process for preparing oxygenated products comprising aldehydes, which have high normal to branched-chain isomer ratios. The process involves using particularly characterized rhodium-containing complex catalysts under a specific combination of carefully controlled reaction conditions. The product aldehydes as made above may be condensed and hydrogenated to form saturated aldehyde dimers thereof.

REFERENCES:
patent: 3489786 (1970-01-01), Dewhirst
patent: 3652614 (1972-03-01), Dewhirst

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