High pressure synthesis of substituted tetrathiafulvalenes

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D33906

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046007849

ABSTRACT:
A process is disclosed for one-step preparation of substituted tetrathiafulvalenes by reaction of carbon disulfide with acetylenic compounds under pressures of at least about 1,000 atmospheres. Substituted tetrathiafulvalenes made by this process are particularly useful as precursors to very pure tetrathiafulvalene, a compound which can complex with tetracyano-p-quinodimethane to form a charge-transfer salt having very high electrical conductivity.

REFERENCES:
patent: 3876662 (1975-04-01), Hartzler
patent: 4312992 (1982-01-01), Green
Narita et al, Int. J. of Methods in Synthetic Organic Chemistry, No. 8 (1976) pp. 489-513.

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