Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing
Patent
1998-06-01
2000-11-28
Siegel, Alan
Organic compounds -- part of the class 532-570 series
Organic compounds
Halogen containing
570257, C07C 2118, C07C 1730
Patent
active
061538035
ABSTRACT:
Halohydrocarbons comprising at least 3 carbon atoms are obtained by reaction between a haloalkane and a haloolefin in the presence of an organonickel compound as catalyst, and optionally in the presence of a solvent. 1,1,1,3,3-Pentachlorobutane can thus be obtained in good yield under mild conditions.
REFERENCES:
M. Asscher et al., "Chlorine Activation by Redox Transfer. Part II..sup.1 The Addition of Carbon Tetrachloride to Olefins", J. Amer. Chem. Soc., 1963, pp. 1887-1896.
Johannus A.M. vanBEEK et al., "Influence of the Amino Substituents of Potentially Bis Ortho Chelating Aryl Ligands (2,6-{R.sup.1 R.sup.2 NCH.sub.2 }.sub.2 C.sub.6 H.sub.3)--on the Synthesis and Properties of Their Organonickel (II) Complexes", Inorg. Chem., 1991, pp. 3059-3068.
Siegel Alan
Solvay ( Societe Anonyme)
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