Process for preparing unsaturated aliphatic esters

Details Process for preparing unsaturated aliphatic esters Process for preparing unsaturated aliphatic esters

1973-06-22

1976-11-09

Killos, Paul J.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252437, 260485R, 260487, 260533A, C07C 6954

Patent

active

039911012

ABSTRACT:
This invention relates to the carbonylation of unsaturated aliphatic halides by the insertion of carbon monoxide into the carbon-halogen bond of said unsaturated aliphatic halide, in the presence of a hydroxylated coreactant, to form an unsaturated, halogen-free, aliphatic ester, using as catalyst homogeneous noble metal complexes with Group VB donor ligands in combination with Group IVB metal halides.

REFERENCES:
patent: 3700706 (1972-10-01), Butter
Monomers Edt. by E. R. Blouk p. 3.
Maitlis, P. M., "The Org. Chem. of Palladium" vol. II, Academic Press, N.Y. 1971 pp. 22-27.

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