Process for the preparation of aldehydes and ketones

Details Process for the preparation of aldehydes and ketones Process for the preparation of aldehydes and ketones

1998-05-21

2000-02-08

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568357, 568399, 568431, 568449, 568470, C07C 4536

Patent

active

060230002

ABSTRACT:
A process for the preparation of vinyl, alkynyl or aryl aldehydes or vinyl, alkynyl or aryl ketones includes reacting vinyl-, alkynyl- and aryl- and -methylene compounds with the aid of a mediator and an oxidant, wherein the mediator is selected from the group of the aliphatic, heterocyclic or aromatic NO or NOH containing compounds.

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Houben-Weyl, vol. E3, pp. 231-247, 1981.
Organic Synthesis, Coll, vol. IV, 1961, p. 30-33.
Patent Abstract of Japan, vol. 015, No. 252 & JP 03081241A Agency of Ind. Science & Technol. Derwent Abstract (#96-301138[31]) corresponding to DE 4445088, Jun. 20, 1996.
Ishii et al, "Alkane Oxidation with Molecular Oxygen . . . ", J. Org. Chem., 1996, 61, pp. 4520-4526.
Potthast, et al, "Selective Enzymatic Oxidation of Aromatic . . . ", J. Org. Chem., 1995, 60, pp. 4320-4321.
Einhorn, et al, "Oxidation of Organic Substrates . . . ",Chem. Commun., 1997, pp. 447-448.
Enzyme List, International Enzyme Nomenclature, Committee of the International Union of Biochemistry and Molecular Biology, Academic Press, Inc.,1992, pp. 24-154.

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