Preparation of carbonyl compounds by isomerization of allyl alco

Details Preparation of carbonyl compounds by isomerization of allyl alco Preparation of carbonyl compounds by isomerization of allyl alco

1988-06-01

1990-08-21

Killos, Paul J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568341, 568375, 568384, 568420, 568443, 568448, 568496, 568414, 568376, 560126, 560174, C07C 4500

Patent

active

049507974

ABSTRACT:
A process for the preparation of carbonyl compounds by catalyzed isomerization of allyl alcohols in a tertiary phosphine or phosphite ester in the presence of a rhodium compound at a temperature of from 80.degree. C. to 180.degree. C., a carrier gas being passed through the reaction mixture and the carbonyl compound being separated from the emergent gas mixture by cooling.

REFERENCES:
patent: 4117016 (1978-09-01), Hughes
Derwent Abstracts: JP 5377/66 (Toyo Rayon), 25.3.66, Production of Carbonyl Compounds.
J. Organometallic Chemistry, 86, C17 (1975).
J. Falbe, New Syntheses with Carbon Monoxide, Springer, Berlin (1980), pp. 107-108.
Bull. Soc. Chim. France, No. 1, 668 (1950).
J. Am. Chem. Soc., 74, 5324 (1952).
S. G. Davies, Organo-Transition-Metal Chemistry, Applications to Organic Synthesis, Pergamon, Oxford (1982), pp. 282-284.

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