Process for synthesizing sucrose derivatives by regioselective r

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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536121, 536115, 536116, 536120, 536122, 536124, 536 186, 536 41, C07H 1300, C07H 2300, C08B 3700, C07G 300

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049507460

ABSTRACT:
Sucrose is reacted with a 1,3-di(hydrocarbyloxy)-1,1,3,3-tetra(hydrocarbyl)distannoxane to produce a 1,3-di-(6-O-sucrose)-1,1,3,3-tetra(hydrocarbyl)distannoxane, which can be acylated to produce a sucross-6-ester.

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Hassner, "Regiospecificity, A Useful Terminology in Addition and Elimination Reactions", J. Org. Chem., 33, No. 7, pp. 2684-2686, Jul. 1968.
David et al., "Regioselective Manipulation of Hydroxyl Groups Via Oranotin Derivatives", Tetrahedron, vol. 41, No. 4, pp. 643-663 (1985).
Wagner et al., "Preparation and Synthetic Utility of Some Organotin Derivatives of Nucleosides", J. Org. Chem., 39, 24 (1974).
Holzapfel et al., "Sucrose Derivatives and the Selective Benzoylation of the Secondary Hydroxyl Groups of 6, 1',6 -Tri-O-Tritylsucrose", S. Afr. Tydskr. Chem., 1984, 37(3), pp. 57-61.

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