Stabilized diperoxyalkanedioic acids and aromatic peroxycarboxyl

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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252186, 568559, C07C17910

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active

042871352

ABSTRACT:
Diperoxyalkanedioic acids and aromatic peroxycarboxylic acids are prepared by reacting a dialkanoic acid or an aromatic carboxylic acid with hydrogen peroxide in sulfuric acid and then producing a desensitizing agent for the peracid in situ by adding alkali metal hydroxide, alkali metal aluminate or an alkaline earth metal hydroxide so that the filtrate is free of sulfuric acid. The resulting salt coats the peracid and the product is desensitized and stable in storage.

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Swern "Organic Peroxides" vol. 1, II and III (1970-1972) pp. 388-392 Wiley-Interscience, N.Y.
Swern "J.A.C.S." vol. 77, pp. 5537-5555 4/1 (1955).
Parker, "J.A.C.S." vol. 79, pp. 1929-1931 (1955).

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