Production of methyl and ethylamines with rhodium-iron catalysts

Details Production of methyl and ethylamines with rhodium-iron catalysts Production of methyl and ethylamines with rhodium-iron catalysts

1979-12-19

1981-02-10

Doll, John

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

C07C 8500

Patent

active

042501164

ABSTRACT:
A heterogeneous process for selectively producing monoamines in which the nitrogen is bonded only to methyl, ethyl, hydrogen or combinations thereof which comprises contacting a mixture of carbon monoxide, hydrogen and a nitrogen-containing compound selected from the group consisting of ammonia, nitric oxide and mixtures thereof with a heterogeneous solid catalyst comprising rhodium and iron. The monoamines of the invention are formed in a collective amount of at least 50 weight percent of the total amine products of the reaction.

REFERENCES:
patent: 3410904 (1968-11-01), Nozaki
patent: 3444203 (1969-05-01), Kurtz
patent: 3636153 (1972-01-01), Enders et al.
patent: 3646148 (1972-02-01), Enders
patent: 3726926 (1973-04-01), Brown et al.
Bashkirov et al, "Iz. Akad. Nauk SSSR, Otdel. Khim Nauk", No. 4, pp. 504-506, (1958).

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