Photocurable acrylic phosphate esters of epoxidized polybutadien

Chemistry: electrical and wave energy – Processes and products – Processes of treating materials by wave energy

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20415922, 525167, 525171, 525922, 526277, C08F23002, C08F27902, C08J 328

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active

042500079

ABSTRACT:
A photosetting composition useful as a coating varnish comprising a modified, epoxidized butadiene polymer, at least one photopolymerizable monomer and a photosensitizer, the modified, epoxidized butadiene polymer comprising (1) an epoxidized butadiene polymer backbone group, (2) 5 to 50 aromatic or cyclocyclic polybasic carboxylic ester side chain groups per 100 butadiene units, each having at least one acryloyl or methacryloyl terminal group and a linking group formed by a reaction between a carboxylic acid radical in the polybasic carboxylic ester and an epoxy radical in the epoxidized butadiene polymer and, optionally, (3) 0 to 50 phosphoric ester additional side chain groups per 100 butadiene units, each having a linking group formed by a reaction between a hydroxyl radical attached to a P atom in the phosphoric ester and an epoxy radical in the epoxidized butadiene polymer.

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patent: 3674545 (1972-07-01), Strolle
patent: 3770602 (1973-11-01), D'Alelio
patent: 3847846 (1974-11-01), Asada
patent: 3855364 (1974-12-01), Steckler
patent: 3884864 (1975-05-01), Matsuda et al.
patent: 3888844 (1975-06-01), D'Alelio
patent: 4146452 (1979-03-01), Weber et al.

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