Catalytic conversion of tertiary butyl hydroperoxide to tertiary

Details Catalytic conversion of tertiary butyl hydroperoxide to tertiary Catalytic conversion of tertiary butyl hydroperoxide to tertiary

1987-09-08

1990-03-27

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

502163, 568910, 568914, 568922, C07C 3112, C07C 29132, C07C 2988, C07C 2704

Patent

active

049122673

ABSTRACT:
Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a base-promoted metal phthalocyanine catalyst, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and a base having a pH greater than about 7.5 when 0.10 mole is dissolved in one liter of water, such as sodium carbonate, sodium acetate, sodium phosphate, ammonium hydrogen phosphate, lithium carbonate, etc.).

REFERENCES:
patent: 3360585 (1967-12-01), Winnick
patent: 3505360 (1970-04-01), Allison et al.
patent: 4508923 (1985-04-01), Taylor et al.
patent: 4547598 (1985-10-01), Sanderson et al.
patent: 4551553 (1985-11-01), Taylor et al.

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