Precipitation polymerization of terpolymers of a vinyl lactam, a

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263171, 526318, C08F 2608

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active

050157086

ABSTRACT:
What is described herein is a precipitation polymerization process and terpolymer products produced thereby. Polymerization is carried out in a reaction mixture of a vinyl lactam, e.g. vinyl pyrrolidone or vinyl caprolactam, a polymerizable carboxylic acid, e.g. acrylic acid or methacrylic acid, and a hydrophobic monomer, e.g. lauryl methacrylate, in a predetermined compositional range, in the presence of a polymerization initiator, and in an aliphatic hydrocarbon solvent, particularly a C.sub.3 -C.sub.10 saturated hydrocarbon, which is branched or unbranched, cyclic or acylic, and, preferably, is heptane or cyclohexane. The terpolymers are obtained in high yield, as a white powder, which can be filtered and dried easily.

REFERENCES:
patent: 3565871 (1971-02-01), Bestian et al.
patent: 4248855 (1981-02-01), Blank et al.
patent: 4482534 (1984-11-01), Blank
patent: 4595737 (1986-06-01), Straub et al.

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