Removing aqueous ammonium sulfate from oxime product

Details Removing aqueous ammonium sulfate from oxime product Removing aqueous ammonium sulfate from oxime product

1979-06-20

1981-03-17

Trousof, Natalie

Organic compounds -- part of the class 532-570 series

Organic compounds

Amino nitrogen containing

210634, 564264, 564267, 564268, C07C13100, C07C13104

Patent

active

042566681

ABSTRACT:
An organic, substantially water-insoluble oxime product is recovered from the liquid reaction mixture of water, ammonium sulfate and the oxime product. First the reaction mixture is separated into a first liquid layer containing an aqueous ammonium sulfate solution and a second liquid layer containing an emulsion of the oxime product as the continuous phase and aqueous ammonium sulfate as the discontinuous phase. These layers are separated and the second liquid layer is contacted with solid ammonium sulfate for a time sufficient to agglomerate the discontinuous phase. The agglomerated discontinuous phase is then removed from the continuous phase. Thereafter, either a lites fraction can be distilled from the continuous phase or the oxime product can be distilled from the continuous phase, or both. The process is particularly applicable to the production of oximes such as Aldicarb oxime, cyclohexanone oxime and methylethylketoxime from aqueous reaction mixtures in which by-product ammonium sulfate is formed.

REFERENCES:
patent: 2820825 (1958-01-01), Hillyer et al.
patent: 3873624 (1975-03-01), Mathew et al.
patent: 3921331 (1976-01-01), Mathew et al.
patent: 3991115 (1976-11-01), Purgason
patent: 4031139 (1977-06-01), Rapp et al.
Jordan, George V., "Coalescing of Fluids Through Porous Materials", Bulletin of the Selas Corporation of America (1965).

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