Phthalimidomethyl cyclopropane carboxylic acid esters

Details Phthalimidomethyl cyclopropane carboxylic acid esters Phthalimidomethyl cyclopropane carboxylic acid esters

1979-05-14

1980-11-04

Daus, Donald G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603405R, 2603474, 260465D, 424274, 424285, 424304, 424305, 560124, C07D20948, A01N 4338

Patent

active

042319323

ABSTRACT:
Novel cyclopropane carboxylic acid esters of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of ##STR2## and benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy, benzyl and halogens, R.sub.1 is selected from the group consisting of hydrogen and methyl, R.sub.2 is selected from the group consisting of monocyclic aryl and --CH.sub.2 --C.tbd.CH,R.sub.3 is an aliphatic of 2 to 6 carbon atoms having at least one double bond, R.sub.4 is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and methyl, n is 0, 1 or 2, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and methyl and S/I indicates that the ring may be aromatic, dihydro or tetrahydro having pesticidal properties, and a process for their preparation.

REFERENCES:
patent: 3709910 (1973-01-01), Matsui
patent: 4166064 (1979-08-01), Kondo et al.
Yura, Y., Chemical Abstracts 85:93937d (1976), Trans-2,2-dimethyl-3(dichloroethenyl)cyclopropane-1-carboxylic acids and their esters.

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