Trihalomethylation of aldehydes

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07C 6800

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043882471

ABSTRACT:
When the reaction of aldehydes with alkali metal trihaloacetates is carried out in the presence of a highly polar aprotic solvent (DMF, DMSO), novel organic alkali metal carbonates, which are precursors of pyrethroid insecticides, are formed in high yields and at a high rate. Novel sulfonates and dihalophosphites, derived from these carbonates have also been claimed.

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