Stabilized metal drier

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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4273855, 526147, C08F 426

Patent

active

050101544

ABSTRACT:
Coating compositions comprising a free radical polymerizable compound, a fatty acid metal drier and a fugitive inhibitor of the metal drier comprising a compound selected from the group consisting of fluoro .beta.-diketones and fluoro .beta.-ketoesters. Upon application of the coating composition as a film to a substrate, the fugitive inhibitor is allowed to volatilize and the metal drier catalyzes the free-radical polymerization of the free radical polymerizable compound.

REFERENCES:
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patent: 4175064 (1979-11-01), Landou et al.
patent: 4180386 (1979-12-01), McCormack et al.
patent: 4590101 (1986-05-01), Knapezyk
patent: 4778864 (1988-10-01), Hardiman
patent: 4810757 (1989-03-01), Hardiman et al.
patent: 4816535 (1989-03-01), Bowers et al.
patent: 4826923 (1989-05-01), Hardiman
"Ionization Constants of Polyfluorinated .beta.-Diketones", by Pashkevich et al., from Zuhrnal Obshchei Khimii, vol. 49, No. 1, pp. 212-215, Jan. 1979.
"Polyfluorinated .beta.-Diketones with a Terminal Hydrogen Atom in the Fluoroalkyl Radical", by Pashkevich et al., from Zhurnal Organicheskoi Khimii, vol. 13, No. 1, pp. 49-52, Jan. 1977.
"Fluorine-Containing .beta.-Diketones", by Pashkevich et al., from Russian Chemical Reviews, 50 (2), 1981.

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