Process for the preparation of N-alkylphthalimide and copolymer

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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548461, 528 26, 528125, 528128, 528185, 524425, 524451, C07D20948, C07D40310

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046237321

ABSTRACT:
Compounds which are bis-(N-alkylphthalimides) are prepared by a new process in which a halogen-containing precursor is heated in the presence of a nickel compound, a reducing agent, for example, metallic zinc, and an organic solvent. The resulting compound is useful in a process for the preparation of a copolymer, in which the compound is reacted with alkali to form a tetraacid, the acid is dehydrated to form a dianhydride, and the dianhydride is reacted with a second dianhydride and a diamine under copolymer-forming conditions.

REFERENCES:
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patent: 3957862 (1976-05-01), Heath et al.
patent: 3972902 (1976-08-01), Heath et al.
patent: 3983093 (1976-09-01), Williams, III et al.
patent: 4017511 (1977-04-01), Williams, III
patent: 4020124 (1977-04-01), Abolins et al.
patent: 4263466 (1981-04-01), Colon et al.
patent: 4273712 (1981-06-01), Williams, III
Williams et al., J. Org. Chem., vol. 43(2), (1978) pp. 250-254.
Colon, et al., Chem. Abstracts, vol. 95 (1981), Entry 62993w.

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