Preparation of 2-(N-formylamino)-propionitrile

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles

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C07C12143

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047015462

ABSTRACT:
2-(N-Formylamino)-propionitrile is prepared by reacting acrylonitrile with formamide in the presence of a basic compound by a process in which the basic compound used is a tertiary nitrogen base.

REFERENCES:
patent: 2461842 (1949-02-01), Olin
patent: 3017425 (1962-01-01), Bortnick
Cyanamid, "The Chemistry of Acrylonitrile", 2nd ed., (1959); Published by American Cyanamid Co., pp. 24 and 197.
Organic Reactions, vol. 5, Chapter#2, "Cyanoethylation", by Bruson (1949), pp. 87, 88, 89, 120.
Bull. Soc. Chim. France 1957, pp. 1108-1110; Mastagli et al.
Houben-Weyl, Methoden der Organischen Chemie, (1957) vol. XI/1, pp. 272-273, and (1958) vol. XI/2, pp. 496-497.

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