Process for forming nitroparaffin

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 7602

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active

044763360

ABSTRACT:
An improved process for forming nitroparaffins by gaseous phase nitration of hydrocarbons higher than methane. The improvement comprises carrying out the nitration in the presence of a small amount of at least one carboxylic acid, preferably acetic acid.

REFERENCES:
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patent: 3869253 (1975-03-01), Lhonore et al.
patent: 3993554 (1976-11-01), Suggitt et al.
patent: 4260838 (1981-04-01), Lhonore et al.
patent: 4313010 (1982-01-01), Lhonore et al.
Nitration Studies, Bachman et al., 35 J. Org. Chem. 4229 (1970).
Vapor Phase Nitration of Aliphatic Ethers, Alcohols, Ketones and Carboxylic Acids, Hass et al., 76 JACS 2692 (1954).
Nitration of Gaseous Paraffins, Hass et al., 28 Ind. & Eng. Chem. 339.

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