Substituted teraselenafulvalenes and high pressure synthesis the

Details Substituted teraselenafulvalenes and high pressure synthesis the Substituted teraselenafulvalenes and high pressure synthesis the

1981-09-18

1983-09-06

Rizzo, Nicholas S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D34500

Patent

active

044028750

ABSTRACT:
A process is disclosed for one-step preparation of substituted tetraselenafulvalenes by reaction of carbon diselenide with acetylenic compounds under pressures of at least about 1,000 atmospheres. Substituted tetraselenafulvalenes made by this process are useful as precursors to very pure tetraselenafulvalene and are useful in forming complexes with certain inorganic anions to provide charge-transfer salts having very high electrical conductivity.

REFERENCES:
patent: 4312991 (1982-01-01), Engler et al.
patent: 4312992 (1982-01-01), Green

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