Stabilization of polyalpha-olefins

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

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585 24, 585 26, C07C 266

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active

051070499

ABSTRACT:
The thermal stability of poly alpha-olefin (PAO) lubricant basestocks are improved by reacting an aromatic compound with the alpha-olefin oligomer. The PAO materials are prepared by oligomerization of olefins such as 1-decene in the presence of a Lewis acid oligomerization catalyst. The resulting lubricant basestock product exhibits high viscosity, viscosity index and low pour point in addition to the unique enhancement in thermal stability. The reaction between the PAO and the aromatic is carried out in the presence of a solid, cyrstalline alkylation catalyst identified by a specific X-ray diffraction pattern. The preferred catalyst for this purpose is the material known as MCM-22.

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