Process for hydroxylating olefins using an osmium carbonyl catal

Details Process for hydroxylating olefins using an osmium carbonyl catal Process for hydroxylating olefins using an osmium carbonyl catal

1982-09-20

1984-12-04

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

2603972, 549243, 560186, 562587, 568458, 568811, 568821, 568833, 568839, 568847, C07C 2904, C07C 3118, C07C 3122, C07C 3142

Patent

active

044866135

ABSTRACT:
A process for hydroxylating olefins, such as ethylene or propylene, using an oxidant selected from organic hydroperoxides, H.sub.2 O.sub.2, and oxygen and a catalyst composition comprising at least one osmium carbonyl catalyst, such as Os.sub.3 (CO).sub.12, and optionally at least one cocatalyst such as NaI, is disclosed.

REFERENCES:
patent: 2773101 (1956-12-01), Smith et al.
patent: 3317592 (1967-05-01), MacLean et al.
patent: 3337635 (1967-08-01), Norton et al.
patent: 3927168 (1975-12-01), Whitehead et al.
patent: 4314088 (1982-02-01), Austin et al.
patent: 4390739 (1983-06-01), Michaelson et al.
patent: 4393253 (1983-07-01), Michaelson et al.

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