Method of preparing tertiary carbinols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3346

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active

044866127

ABSTRACT:
Tertiary carbinols are prepared by reacting an appropriate tertiary halide with water in the presence of a catalytic amount of an emulsifying agent. .alpha.-Methyl-.alpha.-(2,2,2-trichloroethyl)benzyl alcohol is prepared with a high rate of conversion and a low incidence of the formation of an olefin by-product. .alpha.-Methyl-.alpha.-(2,2,2-trichloroethyl)benzyl alcohol is useful as a nitrification inhibitor and as an intermediate in the preparation of structurally related nitrification inhibitors.

REFERENCES:
patent: 2602823 (1952-07-01), Ross
patent: 2606213 (1952-08-01), Ladd
patent: 2975211 (1961-03-01), Girard
patent: 4317672 (1982-03-01), Griffith et al.

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