Process for using t-alkyl peroxy-2-alkyl-2-arylacetates as free-

Details Process for using t-alkyl peroxy-2-alkyl-2-arylacetates as free- Process for using t-alkyl peroxy-2-alkyl-2-arylacetates as free-

1983-05-20

1984-12-04

Bleutge, John C.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

5262323, 525 27, C08F 434, C08F 436

Patent

active

044865805

ABSTRACT:
t-Alkyl peroxy-2-alkyl-2-arylacetates having the general structure A, ##STR1## are used in an improved process for polymerization of ethylenically unsaturated monomers, such as ethylene and vinyl chloride, and for curing of unsaturated polyester resin compositions.

REFERENCES:
patent: 2608570 (1952-08-01), Harman
patent: 3427341 (1969-02-01), Bailey
patent: 3458557 (1969-07-01), Milas
patent: 4092470 (1978-05-01), Oosterwijk
R. A. Wolfe et al., "Properties of Small Ring Free Radicals", I. Thermal Decomposition of .alpha.-substituted Cyclopropyl Percarboxylates, Tetrahedron Letters, No. 14, pp. 1265-1266, 1975.
J. P. Lorand, "Radicals and Scavengers", J. Am. Che. Soc., 96, 2867, (1974).

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