Process for the production of a 1-N((S)-.alpha.-hydroxy-.omega.-

Details Process for the production of a 1-N((S)-.alpha.-hydroxy-.omega.- Process for the production of a 1-N((S)-.alpha.-hydroxy-.omega.-

1974-07-17

1976-04-06

Brown, Johnnie R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260210K, 260210NE, 424180, C07G 300

Patent

active

039488829

ABSTRACT:
Process of producing a 1-N-((S)-.alpha.-hydroxy-.omega.-aminoacyl)-3',4'-dideoxyneamine or -3',4'-dideoxyribostamycin, a useful semi-synthetic antibiotic in which the corresponding 6-O-((S)-.alpha.-hydroxy-.omega.-aminoacyl)-3',4'-dideoxyneamine or -3',4'-dideoxyribostamycine undergoes the acyl-migration reaction by treating with a basic medium.

REFERENCES:
patent: 3792037 (1974-02-01), Kawaguchi et al.
Barton, J. W., "Protection of N--H Bond ect," p. 50, Protective Gps in Org. Chem. McOmie, Plemum Press, NY, 1973.
Wazner and Zook, Syn. Org. Chem., p. 567, parag. 349, Wiley & Sons, N.Y. 1953.
Adams et al., Organic Reactions, Vol. 12, pp. 172-173, 1962, Wiley and Sons, Inc. New York.
Moore et al., Asaserine, "Synthetic Studies I," J.A.C.S. Vol. 76, p. 2884 (1954).

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