Process for butanediols

Details Process for butanediols Process for butanediols

1979-12-14

1983-05-17

Evans, J. E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568561, C07C 3120, C07C17906

Patent

active

043841465

ABSTRACT:
1,4- and 1,2-butanediols are selectively produced by reacting 1,3-butadiene with tert-butyl hydroperoxide in the presence of a cobalt on silica catalyst, followed by catalytic hydrogenation of the di(tert-butylperoxy)butenes obtained thereby.

REFERENCES:
patent: 3896051 (1975-07-01), Mabuchi et al.
Kharash et al., "J. Org. Chem.", vol. 18 (1953), pp. 322-327.
Basolo et al., "Catalysis", Progress in Research (1973), pp. 177 to 185.

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