Introduction of a fluorine atom

Details Introduction of a fluorine atom Introduction of a fluorine atom

1981-07-24

1983-05-17

Roberts, Elbert L.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603973, C07J 100

Patent

active

043839479

ABSTRACT:
Perchloryl fluoride when reacted with the appropriately protected 9.alpha.-hydroxyandrostenedione stereoselectively produces the corresponding 6.beta.-fluoro steroid.

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J. Am. Chem. Soc. 82, 4001 (1960).
Steroids, Fieser and Fieser, Reinhold Pub., New York, 1959, p. 685.
Steroid Reactions, C. Djerasi, Hogan-Day, 1953, Chapter 3, p. 155.

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