Silver bath waste treatment apparatus and method

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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204109, 204149, 204237, 204267, C25C 112, C25C 120, C25B 1500

Patent

active

054095824

ABSTRACT:
Apparatus and methods for removing silver and copper ions from purge streams from silver replacement processes by separately electrowinning silver and copper where silver removal is first effected in an electrowinning cell having a cathode/calomel reference electrode potential between -0.1 and -0.4 volts DC followed by copper removal effected in an electrowinning cell having a cathode/calomel reference electrode potential less than -0.5 volts DC. By this method formation of copper (+1) is prevented in the presence of high concentrations of silver, thus minimizing precipitation of silver metal and formation of copper (+2).

REFERENCES:
patent: 4090935 (1978-05-01), Dunning, Jr. et al.
patent: 4564432 (1986-01-01), Nagai et al.
Edmund C. Potter, Electrochemistry, Principles & Applications, Cleaver-Hume Press Ltd., London (1956) pp. 110-112 and 307.

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