Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1980-03-31
1983-04-26
Helfin, Bernard
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560 9, 560 10, 560 12, 560 13, 560 25, 560 27, 560 28, 560 29, 560 33, C07C125065, C07C125073
Patent
active
043814034
ABSTRACT:
A process for the preparation of N-monosubstituted carbamic acid esters by reacting an unsubstituted carbamic acid ester and an aromatic primary amine at a suitable pressure and reaction temperature in the presence of a monohydric aliphatic alcohol and preferably in the presence of a strongly basic tertiary amine as catalyst. Optionally an inert co-solvent in addition to the alcohol may be employed.
REFERENCES:
patent: 2409712 (1946-10-01), Schweitzer
patent: 2806051 (1957-09-01), Brockway
patent: 2943108 (1960-06-01), Newcomer et al.
Falcone Samuel J.
McCoy John J.
Atlantic Richfield Company
Helfin Bernard
McCaslin Delbert E.
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