Process for the preparation of N-monosubstituted carbamic acid e

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560 9, 560 10, 560 12, 560 13, 560 25, 560 27, 560 28, 560 29, 560 33, C07C125065, C07C125073

Patent

active

043814034

ABSTRACT:
A process for the preparation of N-monosubstituted carbamic acid esters by reacting an unsubstituted carbamic acid ester and an aromatic primary amine at a suitable pressure and reaction temperature in the presence of a monohydric aliphatic alcohol and preferably in the presence of a strongly basic tertiary amine as catalyst. Optionally an inert co-solvent in addition to the alcohol may be employed.

REFERENCES:
patent: 2409712 (1946-10-01), Schweitzer
patent: 2806051 (1957-09-01), Brockway
patent: 2943108 (1960-06-01), Newcomer et al.

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