Isoparaffin-olefin alkylation process

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By condensation of a paraffin molecule with an olefin-acting...

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585714, 585716, 585719, 585720, 585922, 585924, 502 34, 502 41, C07C 262

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active

052929817

ABSTRACT:
A process for isoparaffin-olefin alkylation is provided that permits the use of solid acid catalysts which require frequent regeneration and high isoparaffin/olefin ratios. The process comprises circulating in a reactor a slurry comprising solid acid zeolite catalyst particles (20-2000 microns) and feed of liquid reactants comprising isoparaffins and olefins in an isoparaffin to olefin molar ratio of less than 100, recycling a first portion of said slurry to provide an isoparaffin to olefin molar ratio in the reactor of at least 500, passing a second portion of the slurry to a separating means to separate alkylate product from said solid catalyst particles, and regenerating the catalyst particles.

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patent: 4384161 (1983-05-01), Huang
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patent: 4992615 (1991-02-01), Huss, Jr. et al.
patent: 5095167 (1992-03-01), Christensen
patent: 5157196 (1992-10-01), Crossland et al.

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