Method of synthesizing high surface area vanadium oxides

Chemistry of inorganic compounds – Oxygen or compound thereof – Metal containing

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264 56, C01G 3102

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active

054532612

ABSTRACT:
A method of synthesizing higher surface area vanadium oxides, having the chemical formula V.sub.2 O.sub.13+x, wherein 0.ltoreq.X.ltoreq.0.5, that are employed in fabricating cathode active materials for solid secondary electrochemical cells, is provided. The method includes forming dense NH.sub.4 VO.sub.3 pellets and heating the pellets to decompose the NH.sub.4 VO.sub.3 into V.sub.2 O.sub.5 and NH.sub.3, whereby the NH.sub.3 reduces the V.sub.2 O.sub.5 into vanadium oxides.

REFERENCES:
patent: 4119707 (1978-10-01), Thome et al.
patent: 4486400 (1984-12-01), Riley
patent: 4619822 (1986-10-01), Hammou et al.

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