Process for decomposing N-oxide derivatives producing 5-vinyl-2-

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D207263

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046329943

ABSTRACT:
New process for preparing olefinic lactams by decomposing the corresponding N,N-dimethyl-N-oxides in a suitable solvent in the presence of a base at a temperature of at least 100.degree. C.

REFERENCES:
A. C. Cope and E. R. Trumbull, Olefins from Amines: The Hofmann Elimination Reaction and Amine Oxide Pyrolysis in Organic Reactions, vol. XI, Chapter 5, R. E. Krieger Publ. Co., Huntington, New York, 1975.
Cram et al, JACS, 84, pp. 1734-1735 (1962).
Finar, "Organic Chemistry", p. 301, Longman Green and Co., N.Y., N.Y., (1959).
Cope, JACS, 79, p. 4720 (1957).

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