Process for the transfer of alkyl groups in dialkyl trisulfides

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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568 21, C07C31922

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active

052947432

ABSTRACT:
The alkyl groups of dialkyl trisulfides are exchanged with the alkyl groups of mercaptans by reacting a tertiary dialkyl trisulfide with an alkyl mercaptan having a greater number of carbon atoms in its alkyl group than said trisulfide in the presence of an acidic or basic type catalyst for a time and a temperature sufficient to produce a dialkyl trisulfide having at least one transferred alkyl group from said mercaptan.

REFERENCES:
patent: 2510893 (1946-12-01), Kleiman
patent: 3299146 (1967-01-01), Gilette et al.
M. B. Evans et al., Proceedings Chemical Society, pp. 18-19 (1962).

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