Process for the preparation of polythiophenes by use of ferric s

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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252500, 528403, C08F12806

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052044238

ABSTRACT:
A process for the preparation of a polymer which is electrically conductive and which is based on polythiophene, the process including polymerizing thiophene in a reaction medium including thiophene, from 2.5 to 20 moles of an anhydrous ferric salt per mole of thiophene, from 0.04 to 1 liter of an alkyl halide per gram of thiophene, and from 0.1 to 5% by weight of water introduced into the reaction medium based on the amount of alkyl halide.

REFERENCES:
patent: 4640748 (1987-02-01), Wudl et al.
patent: 4731311 (1988-03-01), Suzuki
Toatsu Chemicals, Inc. Chemical Abstracts, vol. 107, No. 22, Nov. 30, 1987, p. 19, "Synthetic High Polymers", Columbus, Ohio, U.S. No. 199191u, JP-A-62/109,821.
Komatsu K. K., Chemical Patents Index, Basic Abstracts Journal, sec. A: "PLASDOC", No. 87-296,490, Dec. 16, 1987, Derwent Pub. Ltd., London, GB, JP-A-62/209/130.
Mitsui Toatsu Chem., Inc., Patent Abstract of Japan, vol. 11, No. 317 (C-452) [2764] Oct. 15, 1987, "Production of Five-Membered Heterocyclic Compound Polymer", JP-A-62/106,923.

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