Cyclopropylmethanol pesticide

Details Cyclopropylmethanol pesticide Cyclopropylmethanol pesticide

1979-03-15

1980-06-24

Helfin, Bernard

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

560129, 560124, 260544L, 26034611, 260326R, 260465R, 260551S, 562508, 568635, 568640, 568660, 568646, 568592, 424339, 424340, 424341, 424333, 424337, 424320, 424304, 424285, 424274, 568365, 568303, 568420, 568442, 568367, 568329, 568 55, 568 56, C07C 4330

Patent

active

042096421

ABSTRACT:
Compounds of the formula ##STR1## wherein R.sup.1 is an acyl group or certain optionally halo-substituted hydrocarbyl groups, and X is --CH.sub.2 CH(OCH.sub.3).sub.2, --CH.sub.2 CHO, --CH.dbd.CHOR.sup.2 in which R.sup.2 is acyl, --CHO, --C(O)Cl, --C(O)Br or --C(O)OR in which R is H, a salt-forming cation, an alkyl group or the residue of a pyrethroid alcohol are new pesticides or intermediates therefore. The compounds are prepared using a multi-step synthesis starting from the natural terpene, 3-carene.

REFERENCES:
patent: 3636161 (1972-01-01), Robinson
Simmons et al., J.A.C.S., vol. 81, (1959), 4256-4259.
Sevrin et al., Tetrahedron Letters, No. 43, (1976), 3915-3918.

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